| Superman. Then it'd have to be The Hulk.
There is no way Spider-Man can defeat Superman without kryptonite (although Spidey is my favourite).
Reason?
He's stronger, can fly, has super breath, and laser vision eyes. Spidey's web won't affect Superman, as he'll just break through it with his strength.
The Hulk, on the other hand, is pure strength & melee. He is a city-smashing brawler brute. I don't think he can die as his health regenerates.
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